On the Zend Developer Zone there's a new post by Vikram Vaswani about a method for creating PDF files directly from a Zend Framework application (hint: it uses Zend_Pdf).

PHP comes with a number of options to help developers dynamically generate PDF files from within their applications. The Haru and PDFlib extensions offer a complete API for dynamic PDF generation, and there also exist a number of open-source PHP components that can be used for the same purpose. This article will introduce you to one such component, the Zend_Pdf component that ships as part of the Zend Framework, and illustrate how it can be used to perform sophisticated PDF operations from within a PHP application.

The tutorial walks you through some of the introductory steps to using the component (outside of the framework) and create a sample PDF with some basic text. It gets more technical by adding in pictures, text wrapping, drawing lines and shapes, styling text and using things like the My_Pdf_Table feature to easily create tables. There's even a bit at the end about using the properties of the file to set things like title, subject and author.