Two well-known names in the PHP community, Sean Coates and Paul Reinheimer have started up a podcast of their own talking all things web - Pique Web.
There's two episodes so far:
- Interview with Jon Tan of Analog about type, fonts, and how they're changing on the web.
- Interview with Ben Ramsey about content type sensitive returns.
You can either listen to these episodes by downloading the mp3s directly from the page or by subscribing to their feed.